Materials Safety Data Sheet
Anneel-Pak		 MSDS Number: AP1000
dcn: Revision: 1 Last Updated on: 7/10/2009
 
Product Name: Anneel-Pak    
Synonyms: Calcined Petroleum Coke
Manufacturer: Barium & Chemicals, Inc.
PO Box 218
515 Kingsdale Road
Steubenville, Ohio 43952-5218

Phone: 740-282-9776
Fax: 740-282-9161
Web: www.bariumchemicals.com

24-hour Emergency Phone Number: Chemtrec 800-424-9300
CHEMTREC INTERNATIONAL: 703-527-3887
2.) INFORMATION ON INGREDIENTS
  EINECS PERCENT CAS NO:
Anneel-Pak 100% 64743-05-1
3.) HAZARDS IDENTIFICATION
Emergency Overview: Calcined petroleum coke is not considered to be hazardous as defined by OSHA's Hazard Communication Standard 29 CFR 1910.1200. Calcined petroleum coke is considered to be an inert material.
Potential Health Effects: Excessive concentrations of calcined petroleum coke may reduce visibility, cause unpleasant deposits in the eye, ears, and nasal passages, or irritate the skin or mucous membranes by mechanical means. However, normal workplace exposure has not been determined to cause a significant health effect. Calcined petroleum coke, as with many petroleum products, may cause minor skin, eye, or lung irritation, but good hygienic practices can minimize these effects.
4.) FIRST AID MEASURES
Inhalation: Remove to fresh air. If breathing has stopped, administer artificial respiration and supply oxygen. If problem persists, seek medical attention.
Skin Contact: Particles should be periodically washed off of skin with soap and water.
Eye Contact: Immediately flush eyes with plenty of water until irritation subsides. If irritation persists, seek medical attention.
Ingestion Contact: Do not induct vomiting. Immediately give water. Never give anything by mouth to an unconscious person. If symptoms develop, seek medical attention.
This material is not listed as a Carcinogen or Potential Carcinogen by the NTP, IARC or OSHA.
5.) FIRE FIGHTING MEASURES
Extinguishing Media: Water fog, dry chemical, foam, or carbon dioxide.
Special Fire Fighting Procedures: Most reported coke fires have occurred when produced calcined coke is inadequately cooled and stored in a manner that allows the movement of air through the coke bed. May burn if exposed to temperatures greater than 1290F (700C). Should a fire occur, its locations and extent should be determined as quickly as possible. The best procedure is to dig out and remove the coke in the heated zone. The hot coke should be drenched with water as it is exposed.
Fire and Explosion Hazzards: There is a possibility of a steam explosion when introducing water into confined storage such as a silo. There is no dust explosion hazard from calcined petroleum coke. This product also may burn if exposed to temperatures greater than 700 C (1290 F).
Hazardous Combustion Products: Products of combustion may contain carbon monoxide, carbon dioxide, and sulfur dioxide.
Protective Measure in Fire: Do not enter permitted confined space or enclosed area without proper PPE.
6.) ACCIDENTAL RELEASE MEASURES
Personal Precaution in Spill: Wear PPE as directed in Section 10.
Environment: Provisions should be made to prevent washing, draining, or directing material to storm or sanitary sewers.
Spill Clean Up: Material is not toxic and can be picked up by sweeping, shoveling, or vaccuuming.
7.) HANDLING/STORAGE
Usage Precautions:
Usage Descriptions:
Storage Precautions:
Handling Precautions: Coke should be well quenched or cooled before it is stored in a pile out of doors or placed in silos or bins. Storage should be arranged to prevent movement of air through coke. Whenever possible, bulk material in silos should be removed and material drenched in an open area.
8.) EXPOSURE CONTROLS / PERSONAL PROTECTION
Protective Equipment: Dust should be controlled at point of operation.
Process Conditions: OSHA: PEL= 15 mg/m3 as total dust; 5 mg/m3 as respirable fraction. ACGIH: PEL= 10 mg/m3 as total dust; 3 mg/m3 as respirable fraction.
Respirators: Select appropriate NIOSH-approved protection where necessary to maintain exposures below the acceptable limits. Proper respiratory selection should be determined by adequately trained personnel and based on the contaminant(s), the degree of potential exposure, and published respirator factors.
Protective Gloves: None.
Eye Protection: None required. Recommend using dust goggles in areas of high dust concentrations.
Other Protection: None.
Hygienic Work Practices: Material is not toxic and can be picked up by sweeping, shoveling, or vacuuming. Provisions should be made to prevent washing, draining, or directing material to storm or sanitary sewers.
9.) PHYSICAL / CHEMICAL PROPERTIES
Appearance: solid Color: dark gray to black
Odor/Taste: odorless Specific Gravity: 1.8
Solubility: Not soluble in water. Solubility Value: Not applicable
Melting Point: Not applicable. Boiling Point: Not applicable.
Decomp Temp: Flash Point:
pH:    
10.) STABILITY / REACTIVITY
Stability: Stable.
Hazardous Decomp Products: CO, CO2, SO2
Conditions to Avoid: Strong oxidizing acids, other strong oxidants, extreme heat, and open flames
11.) TOXICOLOGICAL INFOMATION
Toxic Dose LD 50: No information found.
Toxicological Info: Petroleum coke was found not to be mutagenic in a rat in vivo Bone Marrow Cytogenic test, a mouse Lymphoma assay, and an Ames Mutagenicity assay.
Inhalation: Petroleum coke was found not to be carcinogenic in monkeys and rats in a two-year inhalation study at concentrations up to 30 mg/m3.
Skin: Petroleum coke was found to be non-carcinogenic in mice in chronic sking painting studies with coke dust.
Eyes: No information found.
Medical Symptoms: Chronic inflammatory changes similar to those produced by non-specific respiratory irritants were observed in some rats at the highest exposure level.
12.) ECOLOGICAL INFORMATION
Toxicity: No information found.
Distribution: No information found
Chemical Fate: No information found.
13.) DISPOSAL CONSIDERATIONS
Disposal Methods: All Federal, State, and Local regulations regarding health and pollution must be followed for disposal of calcined petroleum coke.
General Cleaning: Product may be picked up by sweeping shoveling or vacuuming, however provisions to prevent wahing, draining, or directing material to strom or sanitary sewers should be taken.
14.) TRANSPORTATION INFORMATION
DOT - GROUND TRANSPORTATION:
Proper Shipping Name:ORM-C (Anneel-Pak)
Hazzard Class: Not Regulated.
UN. NO#: Not Regulated.
Packing Group #: Not Regulated./ / Not Regulated.
IATA/IMDG REGULATIONS:
Proper Shipping Name: ORM-C (Anneel-Pak)
Hazzard Class: Not Regulated.
UN. NO#: Not Regulated.
Packing Group #: Not Regulated./ / Not Regulated.
IMDG EMS: Not Regulated.
Shipping Options for this product include:
UPS    FedEx    Plane    Truck    Rail

Transportation Notes: Regulated by water mode only, when temperatures exceed 130 F, Petroleum Coke, Calcined, not regulated by IMO. Must be loaded in cargo vessels when the temperature exceeds 225 F (46 CFR 148.04-17)
15.) REGULATORY INFORMATION
Chemical Inventory Status Part 1
Ingredient: CASNO: TSCA: EINECS: China: Japan: Austrialia:
Anneel-Pak 64743-05-1 No No No No No

Chemical Inventory Status Part 2
Ingredient: CASNO: Korea: DSL: NDSL: Phil.:
Anneel-Pak 64743-05-1 No No No No

Federal, State, International Regulations- Part 1
Ingredient: CASNO: SARA 302: SARA 313
    RQ: TPQ: LIST Chemical Catg:
Anneel-Pak 64743-05-1 No No No No

Federal, State, International Regulations- Part 2
Ingredient: CASNO: RCRA 261.33: TSCA 8(d): CERCLA
Anneel-Pak 64743-05-1 No No No

Additional Items
Chemical Weapons Convention: Acute: TSCA 12(b): CDTA: SARA 311/312: Reactivity: Chronic:
No No No No No No No
Fire Pressure: Austrialian HazChem Code: Poison Schedule: WHMIS:
No No No No No
16.) INFORMATION SOURCES
Information Sources:
Revision Comments:
Other Information: NFPA Rating (0 Least, 1 Slight, 2 Moderate, 3 High, 4 Extreme) Health: 0, Flammability: 1, Reactivity: 0
Disclaimer: Barium & Chemicals, Inc. provides this information as it relates only to the specific product designated herein. All information contained in this MSDS should be provided to the user's employees and/or customers. The information contained herein relates only to the environmental, health and safety precautions for the product and is not intended to be relied upon as technical specifications for commercial or other purposes. Do not use the ingredient information and/or ingredient percentages in this MSDS as product specification. For product specification refer to a Product Specification and/or a Certificate of Analysis provided by or requested from Barium & Chemicals, Inc. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. This information is intended only as a guide to the appropriate precautionaly handling of the product by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a a particular purpose. Conditions of use are beyond the control of Barium & Chemicals, Inc. Users are responsible to verify the applicability of this information under their own operating conditions to determine whether the product is suitable for a particular purpose and assume all risks of use, handling and disposal of the product, or from the publication, reliance upon or other use of the information contained herein. This information is furnished without warranty, expressed or implied;except htat it is accurate to the best knowledge of Barium & Chemicals, Inc. and is based upon data obtained from the manufacturer and/or recognized technical sources. Barium & Chemicals, Inc. expressively disclaims all express or implied warranties of merchantability and fitness for a particular purpose, wiht respect to the product of information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Barium & chemicals, Inc. assumes no responsibility for use, or reliance upon this information. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user.